Homogeneous Catalysis


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1999

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2006

2007

2008

2009


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2009


T. Gianferrara, I. Bratsos, E. Iengo, B. Milani, A. O?tri?, C. Spagnul, E. Zangrando, E. Alessio Synthetic strategies towards ruthenium-porphyrin conjugates for anticancer activity.
Dalton Transactions., 2009, in press DOI: 10.1039/B911393B.
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F. C. Rix, M. J. Rachita, M. I. Wagner, B. Milani, J. C. Barborak, M. Brookhart Palladium(II)-Catalyzed Copolymerization of Styrenes with Carbon Monoxide: Mechanism of Chain Propagation and Chain Transfer .
Dalton Transactions., 2009, in press DOI: 10.1039/B911392D.
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M. Rosa Axet, F. Amoroso, G. Bottari, A. D?Amora, E. Zangrando, F. Faraone, D. Drommi, M. Saporita, C. Carfagna, P. Natanti, R. Seraglia, B. Milani Application of chiral amine-imine ligands in Pd-catalyzed polyketones synthesis: effect of ligand backbone on the polymer stereochemistry.
Organometallics., 2009, 28, 4464-4474.
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2008


B. Milani, C. Crotti, E. Farnetti Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials.
Dalton Trans., 2008, 16, 4659-4663.
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B. Milani, A. M. Masdeu- Bultň Ligand Chirality in Palladium Catalysed Polyketones Synthesis In "Organometallic Chirality"
Edited by G. Pályi, C. Zucchi and L. Caglioti.
Mucchi Editore., 2008, Charter 8, 161-203.
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J. Durand, E. Zangrando, C. Carfagna, B. Milani New atropisomeric N-N ligands for CO/vinyl arene copolymerization reaction.
Dalton Trans., 2008, 16, 2171-2182.
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A. Scarel, M. R. Axet, F. Amoroso, F. Ragaini, C. J. Elsevier, A. Holuigue, C. Carfagna, L. Mosca, B. Milani Subtle Balance of Steric and Electronic Effects for the Synthesis of Atactic Polyketones Catalyzed by Pd-Complexes with meta-Substituted Aryl-BIAN Ligands .
Organometallics., 2008, 27, 1486-1494.
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2007


J. Durand, S. Gladiali, G. Erre, E. Zangrando, B. Milani Palladium chemistry of 2-ferrocenyl-1,10-phenanthroline ligand .
Organometallics., 2007, 26, 810.
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2006


J. Durand, B. Milani The role of nitrogen-donor ligands in the palladium-catalyzed polyketones synthesis .
Coord. Chem. Rev., 2006, 250, 542.
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J. Durand, E. Zangrando, M. Stener, G. Fronzoni, C. Carfagna, B. Binotti, P. C. J. Kamer, C. Müller, M. Caporali, P. W. N. M. van Leeuwen, D. Vogt, B. Milani Long Lived Palladium Catalysts for CO/Vinyl Arene Polyketones Synthesis: A Solution to Deactivation Problems .
Chem-Eur. J., 2006, 12, 7639.
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J. Durand, A. Scarel, R. Seraglia, S. Gladiali, C. Carfagna, B. Binotti, B. Milani Palladium Promoted CO/Ethylene/Styrene Terpolymerisation Reaction: Throwing the Light on the Different Reactivity of the two Alkenes .
Helv. Chim. Acta,, 2006, 89, 1752.
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A. Schätz, A. Scarel, E. Zangrando, L. Mosca, C. Carfagna, A. Gissibl, B. Milani,O. Reiser, High Stereocontrol and Efficiency in CO/Styrene Polyketones Synthesis Promoted by Azabis(oxazoline)-Palladium Complexes .
Organometallics, 2006, 25, 4065.
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S. D. Bergman, I. Goldberg, C. Carfagna, L. Mosca, M. Kol, B. Milani Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Copolymerization .
Organometallics, 2006, 25, 6014.
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2005


A. Bastero, A. Ruiz, C. Claver, A. Bella, B. Milani, B. Moreno, F. A. Jalon, B. R. Manzano
Control of polymer composition in Pd-catalyzed CO/olefin terpolymerization reaction.
Adv. Synth. & Cat., 2005, 347, 839.
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M. Calligaris, E. Zangrando, B. Milani, A. Marson
Stereochemical Investigation of Palladium(II) Complexes with Phenanthroline Ligands: a Molecular Mechanics Approach.
Eur. J. Inorg. Chem., 2005, 704.
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A. Scarel, J. Durand, D. Franchi, E. Zangrando, G. Mestroni, S. Gladiali, C. carfagna, B. Binotti, S. Bronco, T. Gragnoli, B. Milani
Trifluoroethanol: key solvent for palladium-catalyzed polymerization reactions.
J. Organomet. Chem., 2005, 690/8, 2106.
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D. Sirbu, G. Consiglio, B. Milani, P. G. A. Kumar, P. Pregosin, S. Gischig
Palladium complexes with meso-bioxazoline ligands for alternating styrene/CO copolymerisation: Counterion effect.
J. Organomet. Chem., 2005690, 2254.
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A. Scarel, J. Durand, D. Franchi, E. zangrando, G. Mestroni, C. Carfagna, L. Mosca, R. Seraglia, G. Consiglio, B. Milani
Implications of mono- and dinuclear bioxazoline-palladium complexes in the stereocontrolled synthesis of CO/styrene polyketones.
Chem-Eur. J., 200511, 6014.
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2004


B. Milani, A. Marson, A. Scarel, G. Mestroni, J. M. Ernsting, C. J. Elsevier
Facile synthesis of new, stable, palladium-ethyl derivatives containing nitrogen-donor ligands.
Organometallics, 2004, 23, 1974.
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A. Scarel, B. Milani, E. Zangrando, M. Stener, S. Furlan, G. Fronzoni, G. Mestroni, S. Gladiali, C. Carfagna, L. Mosca
Palladium complexes with 3-alkyl-substitued-1,10-phenanthrolines: effect of the ancillary ligand in the CO/olefin copolymerization reactions.
Organometallics, 2004, 23, 5593.
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2003


G. Consiglio, B. Milani
Stereochemical aspects of co-oligomerization and co-polymerization of alkenes with carbon monoxide in “Catalytic synthesis of alkene-carbon monoxide copolymers and cooligomers”.
Ayusman Sen, Kluwer Academic Press, 2003, 6, 189.
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B. Milani, E. Stabon, E. Zangrando, A. Sommazzi, C. Zannoni, G. Mestroni
Polymerisation of polar olefins promoted by organometallic cobalt complexes: free radical or coordinative process?
Inorg. Chim. Acta, 2003, 349, 209.
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B. Milani, A. Scarel, E. Zangrando, G. Mestroni, C. Carfagna, B. Binotti
Cationic palladium complexes with mono- and bidentate nitrogen-donor ligands: synthesis, characterization and reactivity in CO/styrene copolymerization reaction.
Inorg. Chim. Acta, 2003, 350, 592.
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E. Zangrando, M. Trani, E. Stabon, C. Carfagna, B. Milani, G. Mestroni
Synthesis and molecular structure of nickel(II) and cobalt(III) complexes with N-Aryl-diacetyl monoxime.
Eur. J. Inorg. Chem., 2003, 2683.
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B. Milani, A. Scarel, J. Durand, G. Mestroni, R. Seraglia, C. Carfagna, B. Binotti
MALDI-TOF mass spectrometry in the study of CO/aromatic olefins terpolymers.
Macromolecules, 2003, 36, 6295.
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2002


B. Milani, A. Marson, E. Zangrando, J.M. Ernsting, C. J. Elsevier, G. Mestroni
New monocationic methylpalladium(II) compounds with several bidentate nitrogen-donor ligands: synthesis, characterisation and reactivity with CO.
Inorg. Chim. Acta, 2002, 327, 188.
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B. Milani, A. Scarel, G. Mestroni, S. Gladiali, R. Taras, C. Carfagna, L. Mosca
Very stable Pd(II)-(N-N) catalysts for the synthesis of high molecular weight CO/styrene polyketones.
Organometallics, 2002, 21, 1323.
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A. Gsponer, B. Milani, G. Consiglio
The control of stereochemistry in the palladium-catalyzed alternating styrene/carbon monoxide copolymerization: effect of the chirality of the ligand and of the ligand-to-palladium ratio.
Helv. Chim. Acta, 2002, 85, 4074.
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A. Bastero, A. Ruiz, B. Milani, E. Zangrando, C. Claver
Influence of pyridine-imidazoline ligands on the reactivity of Palladium-methyl complexes with carbon monoxide.
Organometallics, 2002, 21, 5820.
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2001


E. Iengo, R. Minatel, B. Milani, L. G. Marzilli, E. Alessio
Metal-mediated self-assembly of molecular squares of porphyrins rimmed with coordination compounds.
Eur. J. Inorg. Chem., 2001, 609.
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B. Milani, G. Mestroni, E. Zangrando
Structural aspects of palladium systems used as catalyst precursors in CO/olefins co- and terpolymerisation reactions.
Croat. Chim. Acta, 2001, 74, 851.
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2000


B. Milani, G. Corso, C. Carfagna, M. Formica, R. Seraglia, G. Mestroni
Highly efficient catalytic system for the CO/styrene copolymerization: towards the stabilization of the active species.
Organometallics, 2000, 19, 3435.
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A. Sessanta o Santi, B. Milani, E. Zangrando, G. Mestroni
Synthesis and crystal structure of a palladium metallacyclic complex: a key intermediate in the carbonylation of azobenzene to N-phenylurethane.
Eur. J. Inorg. Chem., 2000, 2351.
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E. Iengo, B. Milani, E. Zangrando, S. Geremia, E. Alessio
Novel ruthenium building blocks for the efficient modular construction of heterobimetallic molecular squares of porphyrins.
Angew. Chem. Int. Ed., 2000, 39(6), 1096.
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B. Milani, F. Paronetto, E.Zangrando
Ligand driven S,P structural rearrangements of organopalladium complexes: Their relevance to the CO/styrene copolymerisation reaction.
J. Chem. Soc., Dalton Trans., 2000, 3055.
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1999


B. Milani, G. Mestroni
Pd(II) Complexes with Bidentate Nitrogen-donor Chelating Ligands: Very Versatile and Active Catalyst Precursors for the CO/olefin Co- and Terpolymerization Reactions.
Comments on Inorganic Chemistry
; 1999, 20, 301.
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B. Milani, G. Corso, E. Zangrando, L. Randaccio, G. Mestroni
Crystal structure and dynamic behavior of a new class of monocationic organometallic Pd(II) compounds with two molecules of bidentate ligands: [Pd(L-L)(N-N)(CH2NO2)][PF6] (L-L = N-N, dppp).
Eur. J. of Inorg. Chem
, 1999, 2085.
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A. Macchioni, G. Bellachioma, G. Cardaci, M. Travaglia, C. Zuccaccia, B. Milani, G. Corso, E. Zangrando, G. Mestroni, C. Carfagna, M. Formica
Counterion effect on CO/styrene copolymerization catalyzed by cationic palladium(II) organometallic complexes: an interionic structural and dynamic investigation based on NMR spectroscopy.
Organometallics
, 1999, 18, 3061.
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