TABLE S5
Bond lengths (Å) and angles (°) for Group VIA metal sulfoxide complexes a
| M | M-S | S-O | S-C | M-S-O | M-S-C | C-S-C | O-S-C | Ref. | |
| Cr(0) | 1 | 2.331(1) | 1.486(3) | 1.811(5) | 114.6(1) | 116.4(2) | 92.6(2) | 106.2(2) | 194 |
| 1.811(4) | 117.6(2) | 106.9(2) | |||||||
| M | M-O | S-O | S-C | M-O-S | C-S-C | O-S-C | Ref. | ||
| Mo(II) | 2 | 2.127(5) | 1.524(5) | 1.776(8) | 128.4(3) | 98.6(4) | 102.8(4) | 195 | |
| 1.775(7) | 103.2(4) | ||||||||
| 2.140(4) | 1.518(5) | 1.755(8) | 130.9(3) | 99.4(5) | 103.5(4) | ||||
| 1.760(9) | 104.8(4) | ||||||||
| Mo(VI) | 3 | 2.215(5) | 1.505(6) | 1.78(2) | 128.5(4) | 97.2(8) | 104.2(8) | 199 | |
| 1.79(2) | 103.3(6) | ||||||||
| 4 | 2.263(8) | 1.521(8) | 1.76(1) | 120.5(4) | 99.2(6) | 103.6(6) | 200 | ||
| 1.77(2) | 107.1(6) | ||||||||
| 2.220(8) | 1.528(8) | 1.78(2) | 131.2(4) | 98.6(6) | 104.2(6) | ||||
| 1.74(2) | 104.1(6) | ||||||||
| 5 | 2.257(4) | 1.519(5) | 1.762(9) | 124.2(3) | 98.4(4) | 102.5(3) | 202 | ||
| 1.764(9) | 106.5(3) | ||||||||
| 2.268(4) | 1.528(5) | 1.771(8) | 126.3(3) | 98.7(5) | 102.7(3) | ||||
| 1.736(9) | 106.0(4) | ||||||||
| 6 | 2.234(3) | 1.526(2) | 1.779(5) | 130.8(2) | 98.8(2) | 102.2(2) | 203 | ||
| 1.775(3) | 104.7(2) | ||||||||
| 7 | 2.357(3) | 1.536(3) | 1.819(4) | 117.0(2) | 92.5(2) | 104.8(2) | 205 | ||
| 1.801(5) | 104.8(2) | ||||||||
| 8 | 2.382(3) | 1.517(4) | 1.766(7) | 121.9(2) | 99.2(3) | 105.4(3) | 206 | ||
| 1.788(7) | 105.4(3) |
______________________________________________________________________________
| n | 10 | 15 | 10 | 9 | 20 | ||
| s | 0.008 | 0.020 | 4.9 | 0.6 | 1.4 | ||
| <x>s | 1.524 | 1.774 | 126 | 98.7 b | 104.3 | ||
| s(<x>s) | 0.002 | 0.005 | 2 | 0.2 | 0.3 |
a Figures in italics are not included in the calculation of the mean, referring to TMSO.
b Unweighted mean.
1 Cr(CO)5(TMSO). 2 trans,cis,cis-MoBr2(NO)2(DMSO)2. 3 [{Mo3CuS4}{S2P(OEt)2}3(I)(m2-OOCMe)(DMSO)]. 4 [MoO2(m-O)(pentanetrionato)(DMSO)2].5 Mo3O9·4DMSO. 6 [{MoO2(OEt)2(DMSO)}2]. 7 [MoO2{C5H3N-2,6-(CH2S)2}(TMSO)]. 8 [MoO2{diphenyl ethanolato)pyridine}(DMSO)].
