Publications References

  1. (Single institute publication, TU/e) Maria Caporali, C. Müller, S. Staal, D.M. Tooke, A.L. Spek, P.W.N.M. van Leeuwen, “New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization” Chem.Commun, 2005, 3478.

This work relates to Task 1, 2, 9, 11.


  1. (Single institute publication, CNR.ICCOM) Bianchini C., Meli A., Oberhauser W., Parisel Sebastien, Passaglia E., Ciardelli F., Gusev O. V., Kal’sin A. M. “Ethylene Carbonylation in Methanol and in Aqueous Media by Palladium(II) Catalysts Modified with 1,1’-Bis(dialkylphosphino)Ferrocenes” Organometallics 2005, 24, 1018.

This work relates to Tasks 1, 2, 3.


  1. (Joint publication, CNR.ICCOM/URV) Bianchini C., Brüggeller P., Claver C., Czermak G., Dumfort A., Meli A., Oberhauser W., Garcia Suarez E. J. “Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low-molecular-weight alternating polyketones via catalytic CO/ethene copolymerisation” Dalton Trans. 2006, 2964.

This work relates to Task 1, 2, 3.


  1. (Single institute publication, CNR.ICCOM) Barbaro P., Bianchini C., Giambastiani G., Parisel Sebastien "Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines" Coord. Chem. Rev. 2004, 248, 2131.

This work relates to Tasks 1, 2.


  1. (Single institute publication, CNR.ICCOM) Bianchini C., Meli A., Oberhauser W., Parisel Sebastien, Gusev O. V., Kal’sin A. M., Vologdin N. V., Dolgushin F. M. “Methoxycarbonylation of styrene to methyl arylpropanoates catalyzed by palladium(II) precursors with 1,1’-bis(diphenylphosphino)metallocenes” J. Mol. Catal. A 2004, 224, 35.

This work relates to Tasks 1, 2, 5.


  1. (Joint publication, URV/TU/e)Ester Guiu, Maria Caporali, Munoz B., Müller C., Lutz M., Spek A. L., Claver C., van Leeuwen P. W. N. M. “Electronic Effect of Diphosphines on the Regioselectivity of the Palladium-Catalyzed Hydroesterification of Styrene” Organometallics 2006, 25, 3102.

This work relates to Task 2, 5.


  1. (Single institute publications, URV) Cyril Godard, Ruiz A. and Claver C. “Systematic Study of the Mehoxycarbonylation of Styrene Catalyzed by Palladium Systems Containing Chiral Ferrocenyl Diphosphine Ligands” Helv. Chim. Acta, 2006, 89, 1610.

This work relates to Task 1, 2, 5.


  1. (Single institute publications, URV) Muñoz B., Cyril Godard, Marinetti, A., Ruiz A. and Claver C. “Pd-catalysed methoxycarbonylation of vinylarenes using chiral monodentate phosphetanes and phospholane as ligands.” Adv. Synth. & Cat., submitted for publication.

This work relates to Task 1, 2, 5.


  1. (Joint publication, UNITS/TU/e) Durand, Jérôme; Zangrando, E.; Stener, M.; Fronzoni, G.; Carfagna, C.; Binotti, B.; Kamer, P. C. J.; Müller, C.; Caporali, Maria; van Leeuwen, P. W. N. M.; Vogt, D.; Milani, B. “Long Lived Palladium Catalysts for CO/Vinyl Arene Polyketones Synthesis: A Solution to Deactivation Problems” Chem.-Eur. J. 2006, 12, 7639.

This work relates to Task 2, 4, 11.


  1. (Joint publication, ETHZ/UNITS) Sirbu, Doina; Consiglio, G.; Milani, B.; Kumar, P.G.A.; Pregosin, P.; Gischig, S. “Palladium complexes with meso-bioxazoline ligands for alternating styrene/CO copolymerisation: Counterion effect.” J. Organomet. Chem., 2005, 690, 2254.

This work relates to Task 2, 4, 11.


  1. (Joint publication, UNITS/ETHZ) Scarel, A.; Durand, Jérôme; Franchi, D.; Zangrando, E.; Milani, B.; Mestroni, G.; Carfagna, C.; Seraglia, R.; Consiglio, G. “Implications of mono- and dinuclear bioxazoline-palladium complexes in the stereocontrolled synthesis of CO/styrene polyketones.” Chem.-Eur. J., 2005, 11, 6007.

This work relates to Task 2, 4, 11.


  1. (Joint publication, URV/UNITS) Bastero, A.; Claver, C.; Ruiz, A.; Castillon, S.; Daura, E.; Bó, C.; Zangrando, E. “Insights into CO/styrene copolymerization through the use of Pd(II) catalysts containing modular pyridine-imidazoline ligands.” Chem. Eur. J., 2004, 10, 3747.

This work relates to Task 1, 2, 4.


  1. (Joint publication, URV/UNITS) Bastero, A.; Ruiz, A.; Claver, C.; Bella, Antonio; Milani, B.; Moreno, B.; Jalón, F. A.; Manzano, B. R. “Control of polymer composition in Pd-catalysed CO/styrene/ethylene terpolymerization.” Adv. Synth. & Cat., 2005, 347, 839.

This work relates to Task 6, 11.


  1. (Single institute publication, UNITS) Durand Jérôme, Scarel A., Seraglia R., Gladiali S., Carfagna C., Binotti B., Milani B. “Palladium Promoted CO/Ethylene/Styrene Terpolymerisation Reaction: Throwing the Light on the Different Reactivity of the two Alkenes” Helv. Chim. Acta, 2006, 89, 1752.

This work relates to Task 6, 11.


  1. (Single institute publication, UNITS) Milani, B., Scarel, A., Durand, Jérôme, Mestroni, G., Seraglia, R., Carfagna, C., Binotti, B. “MALDI-TOF mass spectrometry in the study of CO/aromatic olefins terpolymers.” Macromolecules, 2003, 36, 6295.

This work relates to Tasks: 6, 11.


  1. (Joint publication, UNITS/UAMSK) Scarel A., Axet M. Rosa, Ragaini F., Elsevier C. J., Holuigue A., Carfagna C., Milani B. “Subtle balance of Steric and Electronic Effects for Synthesis of Atactic Polyketones Catalyzed by Pd-Complexes with meta-Substituted Aryl-BIAN Ligands” in preparation.

This work relates to Task 1, 2, 4, 11.


  1. (Single institute publication, UNITS) Schätz Alexander, Scarel A., Zangrando E., Mosca L., Carfagna C., Gissibl A., Milani B., Reiser O. “High Stereocontrol and Efficiency in CO/Styrene Polyketones Synthesis Promoted by Azabis(oxazoline)-Palladium Complexes” Organometallics, 2006, 25, 4065.

This work relates to Task 2, 4, 11.


  1. (Single institute publication, URV) Gomez, M., Muleer, G., Fauvier, I., Lopez, F., Ruiz A., Claver C., Antonio Bella “First palladium allylic systems containing chiral imidazolyl-pyridine ligands. Structural studies and catalytic behavior” Eur. J. Inorg. Chem., accepted for publication.

This work relates to Task 2, 5.


  1. (Single institute publication, ULP) Agostinho Magno, Andrei Banu, Braunstein, P., Welter, R. and Morise, X. “New palladium complexes with phosphino-and phosphinito-pyridine ligands” Acta Cryst., 2006, C62, m81.

This work relates to Task 1, 2.


  1. (Single institute publication, ULP) Agostinho Magno and Braunstein, P. “Structurally Characterized Intermediates in the Stepwise Insertion of CO/Ethylene or CO/Methyl Acrylate into the Metal-Carbon Bond of Pd(II) Complexes Stabilized by (Phosphinomethyl)Oxazolinetype Ligands” Chem.Commun., accepted for publication.

This work relates to Task 1, 2, 6.


  1. (Single institute publication, ULP) Agostinho Magno and Braunstein, P. “Phosphinito- and Phosphonito-oxazoline Pd(II) Complexes as CO/Ethylene Insertion Intermediates: Synthesis and Structural Characterization” in preparation.

This work relates to Task 1, 2, 3.


  1. (Single institute publication, ULP) Agostinho Magno and Braunstein, P. “Palladium(II) intermediate complexes in CO/ethylene or CO/methyl acrylate insertion containing the new P,N-type ligand (2-oxazoline-2-ylmethyl)di-isopropylphosphine” in preparation.

This work relates to Task 1, 2, 3.


  1. (Single institute publication, ETHZ) Sirbu Doina, Consiglio G., Gischig S. “Palladium and nickel complexes of (P,N)-ligands based on quinolines: Catalytic activity for polymerization and oligomerization” J. Organomet. Chem., 2006, 691, 1143.

This work relates to Task 1, 2, 3, 9.


  1. (Single institute publication, UAMSK) Michela Fusco, Michael R. Eberhard, Elsevier C. J., Kooijman H., Spek. A. L. “Imino- and aminophosphine-carbene complexes of palladium(II)” in preparation.

This work relates to Task 1, 2, 3.

  1. (Single institute publication, UAMSK) Michael R. Eberhard, Duran Pachon L., Rothenberg G., Elsevier C. J., Eastham G., Kooijman H., Spek A. L. “Palladium complexes of acyclic diamino- and aminooxycarbenes by reaction of functionalised phosphines with isonitriles.” Submitted.

This work relates to Task 1, 2, 3.


Joint Publications and Patents

The five most significant joint publications of the overall Network activity

  1. (Joint publication, URV/TU/e) Ester Guiu, Maria Caporali, Bianca Munoz, Christian Mueller, Martin Lutz, Anthony L. Spek, Carmen Claver, Piet W.N.M. van Leeuwen, “Electronic Effect of Diphosphines on the Regioselectivity of the Palladium-Catalyzed Hydroesterification of Styrene” Organometallics 2006, 25, 3102.

This work relates to Task 2, 5.


  1. (Joint publication, UNITS/TU/e) Durand, Jérôme; Zangrando, E.; Stener, M.; Fronzoni, G.; Carfagna, C.; Binotti, B.; Kamer, P. C. J.; Müller, C.; Caporali, Maria; van Leeuwen, P. W. N. M.; Vogt, D.; Milani, B. “Long Lived Palladium Catalysts for CO/Vinyl Arene Polyketones Synthesis: A Solution to Deactivation Problems” Chem.-Eur. J. 2006, 12, 7639.

This work relates to Task 2, 4, 11.


  1. (Joint publication, CNR.ICCOM/URV) Bianchini C., Brüggeller P., Claver C., Czermak G., Dumfort A., Meli A., Oberhauser W., Garcia Suarez E. J. “Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low-molecular-weight alternating polyketones via catalytic CO/ethene copolymerisation” Dalton Trans. 2006, 2964.

This work relates to Task 1, 2, 3.


  1. (Joint publication, UNITS/ETHZ) Scarel, A.; Durand, Jérôme; Franchi, D.; Zangrando, E.; Milani, B.; Mestroni, G.; Carfagna, C.; Seraglia, R.; Consiglio, G. “Implications of mono- and dinuclear bioxazoline-palladium complexes in the stereocontrolled synthesis of CO/styrene polyketones.” Chem.-Eur. J., 2005, 11, 6007.

This work relates to Task 2, 4, 11.


  1. (Joint publication, URV/UNITS) Bastero, A.; Ruiz, A.; Claver, C.; Bella, Antonio; Milani, B.; Moreno, B.; Jalón, F. A.; Manzano, B. R. “Control of polymer composition in Pd-catalysed CO/styrene/ethylene terpolymerization.” Adv. Synth. & Cat., 2005, 347, 839.

This work relates to Task 6, 11.

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15/Dec/2006 - Crevatin rcrevatin@units.it